GreenHouse Effect

Simply

The temperature of the earth as seen from space is the average temperature (or more accurately average heat energy) of all the molecules and surfaces emitting IR to space. If this average temperature increases more IR is emitted and the earth cools. If this average temperature decreases, less IR is emitted and the earth warms.

The temperature of molecules is determined by the lapse rate which means the temperature in the lower atmosphere drops by about 6.5C/km.

If there are more molecules present in the atmosphere like CO2 which are active in the IR, then they tend to block IR from lower levels and cause more emission from higher levels. In effect the average radiation height increases and therefore IR is emitted from colder levels, less IR energy is emitted and so the earth warms up.

We can calculate the change in IR caused by a doubling of CO2 in the atmosphere. This amounts to change in average radiation level of about 150m.

Introduction

Over the years I have seen many people arguing about how the Greenhouse effect works and from these discussions it is clear that most people misunderstand it. That is not to say that adding a greenhouse gas like CO2 to a typical atmosphere like the earth’s should not cause warming. Instead, whilst this “greenhouse” warming is a nice & simple way to explain to an average person on street how increasing CO2 would cause warming it is not true any other sense than it is what tends to happen and is certainly not a “law” of nature.

Yes it works to indicate what is happening, unfortunately as soon as people start talking about the detailed mechanisms behind it or worse using it to predict behaviour, this simple explanation fails and cause a lot of senseless argument because it does not and cannot encompass the true complexity of the situation.

So, this guide is intended to go one step beyond the simple “man on the street” explanation.

Greenhouse gases are not really “greenhouses”

It’s indicative that this “greenhouse gas theory” is not the best science when I have to start by saying that the mechanism by which greenhouse warm plants is not at all the same physical mechanism as we are discussing here. The reality is that whilst the sun both warms a greenhouse like the earth, the greenhouse works by physically restraining the gases so that the hot gases are kept within the confines of the greenhouse.

Greenhouse Gas “theory”

Typically websites will show diagrams like the one below labelling this mechanism as a “theory” as if it were based on some fundamental law of nature. So let’s just recap this “theory”.

noddy

Typical outline of the “greenhouse gas theory”.

Shown above is the normal outline of the “Greenhouse gas” theory. The sun is shown shining on the earth through the atmospheric layer. The energy flowing in then disperses either heading back into space or as shown to the top, being “trapped” by greenhouse gases which then “back radiate” the trapped heat down to the earth’s surface.

As a qualitative description of what happens, this illustrates many of the key energy flows, but it is clearly not quantitative. Such descriptions seldom if ever show any kind of equations, formulas or any other mechanism by which any of these flows can be calculated or justified. They appear to come from nowhere, their meaning is obscure and as such they are in effect hand-waving arguments which give little if any scientific insight to what is actually happening.

They are at best illustrative, at worst misleading.

False Criticisms based on Laws of Thermodynamics

The most often heard criticism raised against this depiction of the energy flow, is that “warming” is said to occur as a result of back radiation of heat trapped by greenhouse gases. This requires heat to move from a colder region (the atmosphere) to the warmer surface of the earth. This is felt to break the second law of thermodynamics as it is often stated:

the second law of thermodynamics says that heat flows naturally from an object at a higher temperature to an object at a lower temperature, and heat doesn’t flow in the opposite direction of its own accord.

However, the heat flow is actually from the surface to the air and back again and the net flow when all things are considered is from the hotter surface to the colder atmosphere. It is not that heat is flowing from the colder area to warmer, but that the colder object is reducing the flow away from the hotter (much as a coat or blanket will be colder than a person, but reduces the flow from away from them to the environment)

The physical basis of CO2 interaction with IR.

CO2_vibration

Various vibration modes of CO2 molecule and their characteristic wavelength.

In order for molecules to interact with electromagnetic radiation like IR, they require to have a charge dipole. That is to say, the average position of positive charges must be offset to that of the average position of negative charges. Looking at the diagram to the right showing the normal vibrational modes, it is clear that Carbon dioxide doesn’t have a molecular dipole in its ground state where the carbon is mid-way between the two oxygen atoms. However, some CO2 vibrations where the oxygen and carbon atoms move in different directions do produce a structure with a molecular dipole.

Looking at the diagram, a symmetrical stretch where both oxygen atoms move in opposition to each other leaves the average position of all oxygen atoms unchanged. Therefore the vibration associated with this at 1388cm-1 does not interact with electromagnetic radiation. However where the oxygen atoms move perpendicular to the axis in the bending vibration, their average position moves relative to the carbon and so the associated wavelength of 667cm-1 interacts strongly. Likewise, where the central carbon moves back and forth toward each oxygen we get strong interaction at 2349cm-1 .

Because of this, CO2 strongly interacts with infra-red radiation. This interaction can be seen in the spectrum of radiation leaving the earth where there are obvious “holes” where the spectrum is deficient at various frequencies. The CO2 hole can be clearly seen around 667cm-1 as well as those for other gases.

Absorption spectra of electro-magnetic radiation leaving the earth’s surface with red line representing spectrum of idealised black body.

Two way energy flow into greenhouse gases

Having a vibration mode where the average positive and negative charges allows CO2 to absorb radiation as below:

Electromagnetic radiation being absorbed by a CO2 molecule

Electromagnetic radiation being absorbed by a CO2 molecule

However, but addition when the CO2 molecule is vibrating that dipole moment acts like a radio antenna and so it can also emit radiation.

CO2_emit

A CO2 molecule which is already vibrating may emit electromagnetic radiation.

So, the very physical property that enables a molecule to absorb radiation at the wavelength of its vibrational modes is also the same physical property which means that if it already is vibrating, then it can release this energy as electromagnetic radiation.

To show that these must be equal, consider an infinite universe with nothing else but CO2 molecules all at the same temperature. The chance of 667cm-1 radiation being emitted must be exactly the same chance of it being absorbed. Therefore at the same temperature, the probability of absorption is the same as emission. Therefore if a gas is an absorber of radiation, then** it is also an emitter of that same radiation.

**at least for a simple molecule like CO2

Blackbody radiation

According to the Stefan Boltzmann principle, a body at of uniform temperature radiates energy per unit of area according to the equation:

E/A = εσT4

Where E is energy (joules), A is area of body (m2), σ is Stefan Boltzmann constant (
~5.67x 10-8 Wm-2K-4), T is temperature (Kelvin) and ε is a fraction which ranges between zero and one. ε varies between surfaces and depends on a variety of factors from chemical make up to topology of the surface and the range of wavelengths being considered. In general, the more complex the chemical composition of the surface and the more complex the topology, the higher the value of ε.

Emissivity in Surfaces

??

Incoming energy (E) is either absorbed by surface or reflected.

Because those surfaces which most readily give off radiation at any frequency will usually be equally able to absorb radiation at the same frequency, in most cases the value of ε in the above equation is also the fraction of incoming electromagnetic radiation at the same frequencies that will be absorbed. So for light incident on a surface as shown right for an incident electromagnetic flow E onto the surface, the absorption will be:

Eabsorbed = εE

And therefore as the remainder has to go somewhere, it will be reflected so:

Ereflected = (1-ε)E

Emissivity in Gases

??

Incoming energy (E) is either absorbed by CO2 or diffracted around and  continues on.

Like a surface, a gas also has an emissivity corresponding to the fraction of light it will absorb and that which it will not. However, unlike a surface, a gas molecule is too small to reflect the non absorbed light and instead the light that is not absorbed but diffracts around the molecule giving equations:

Eabsorbed = εE

Enon-absorbed = (1-ε)E

How does greenhouse warming work?

To explain the mechanism of greenhouse warming, we are going to have the simplest possible planet and atmosphere. The planet is a uniform body and it’s atmosphere consists of a single molecule of CO2 (if necessary consider it embedded in an otherwise inert gas with no absorption or emissions at the wavelengths of interest)

Earth-SingleCO2

Energy flows for our one molecule atmosphere showing position of observer looking toward earth past the single CO2 molecule.

Here we have a planet with a sun (yellow), which for simplicity we will consider to be a point source. It shines onto the planet (black) as well as the single molecule of CO2 (red).

Everything is at thermal equilibrium with the planet at temperature TE and the CO2 molecule at TC.

According to the Stefan Boltzmann principle, a body radiates energy per unit of area according to the equation:

E/A = εσT4

View of planet from observer with single CO2 molecule partly obscuring view of planet surface

And so I have marked on the corresponding energy flows that would be seen by an observer away from the earth.

Viewed from the observer, the earth would look as the diagram to the right. One side of the huge circular shape of the earth visible in full except for one part obscured by the single CO2 molecule. And for our purposes, we will assume the CO2 molecule is so close to the earth that:

  • Either: It obscures the earth from the observer
  • Or  the earth obscures the CO2 molecule

How does this single molecule affect the temperature of the earth?

(1) Heat flow per unit area from earth (E) = εEσTE4

(2) Heat absorbed by CO2 per unit area = εCE

(3) Non absorbed heat flowing past CO2 per unit area = (1-εC)E

(4) Heat emitted from CO2 per unit area = εCσTC4

Combining (1) and (3):

(5) Non absorbed heat past CO2 per area = (1-εC) εEσTE4

So total heat flow out from and past CO2 molecule (per unit area) is:

(6) EC = (1-εC) εEσTE4 + εCσTC4

So the change in heat flow caused by the CO2 (per unit area) is flow from earth – heat flow past CO2:

δE = EC – E

(7) δE =  ( (1-εC) εEσTE4 + εCσTC4 ) – εEσTE4

Simplifying we get:

δE = εEσTE- εC εEσTE4  + εCσTC4 – εEσTE4  
(9) δE = εCσTC4 – εC εEσTE4

So if δE is positive, then the CO2 molecule has caused a net increase in heat flow from the earth and so there is a net cooling effect and if δE is negative, then heat flow from the earth has decreased and there is a net warming effect. So (eliminating σ):

[ εCσTC4 – εC εEσTE4 >  0  ⇒ Global Cooling

[ εCTC4 – εC εEσTE4 0  ⇒ Stasis

[ εCTC4 – εC εEσTE4<  0  ⇒ Global Warming

Rearranging and removing σ, the condition for global warming is that:

(10) TC4 / εETE4 <  1

or

(11) ( TC / TE ) <   εE 0.25

and so if

TC  <  TE  εE 0.25  ⇒ Global Warming

The earth’s emissivity is given as ocean: 0.90 to 0.93 (link) and land surface 0.96 (link). Assuming 70% of the planet is sea, this gives an average emissivity of approximately

εE = (0.7 *(0.9+0.93)/2) + 0.3 * .96 ~= 0.93

So if the average surface temperature (TE) is 15C (288K), then we arrive at the following:

TC  <  288 x 0.930.25

TC  <  282K (9C)

Based on a planet with the earth’s average emissivity and a surface temperature of 15C but unlike the earth, with a uniform surface temperature, then the addition of one molecule of CO2 would depend on its temperature as follows:

TC  >  9C  ⇒ Global Cooling

TC  = 9C  ⇒ Stasis

TC  <  9C  ⇒ Global Warming

Is CO2 a global warming gas?

stdatm_GW_GC

The threshold between CO2 causing warming and cooling for the average emissivity of the earth ( ε=0.93)

As we can see from the calculations above, adding a gas that interacts with infra-red has an affect on the atmosphere, but that affect does not necessarily lead to global warming. Whether or not there is global warming is affected by the temperature of the atmosphere (and earth’s surface emissivity/albedo).

Radiative Height

By now you should understand that the key thing that is changing the outgoing radiation is the change in the temperature of the molecules which in turn changes by their height in the atmosphere. The temperature profile is due to the lapse rate which is in effect the change of heat energy to potential energy. (In order to lift up the mass of air, energy must come from somewhere).

Having looked at at an atmosphere with one molecule we can extend this simply to an atmosphere by saying that the average temperature of a planet as viewed from space is the average temperature (or to be more precise average heat energy) of all the last molecules or surfaces that emitted radiation into space. But where are these?

We can work this out because the situation for emission is the same as absorption. In other words, if we were to shine an “IR torch” down into the atmosphere, the IR would be gradually absorbed as it passed down. And the emission curve will be identical. Below is plotted a series of emission/absorption curves for our atmosphere showing how it changes as the proportion of greenhouse gases change:

crossExcept at the ground surface, the curves are for all practical purposes the same. As such the effect of changing greenhouse gas concentration is merely to raise of lower the entire curve by a fixed amount. The scale of this change is not large and would be about 150m for a doubling of CO2.

But don’t forget those white fluffy things called clouds

However, before finishing this article, I would just like to mention those things we call clouds. The above analysis is based on a highly unrealistic planet without clouds. Clouds have a significant effect on earth as they change the albedo of the earth from around 0.93 to 0.7. This would then mean that for CO2 to cause warming, the temperature of that CO2 needs to be below:

TC  <  288 x 0.70.25

TC  <  263K (-10C)  ⇒ global warming

The threshold for an albedo of 0.7 ((earth with clouds)

The threshold between CO2 causing warming and cooling for an albedo of 0.3 ( ε = 0.7 i.e. earth with clouds)

Now, much more of the lower atmosphere where the atmosphere is more dense could cause cooling (albeit much is below cloud layer). Also we start to see cooling layers at 50km as well as the more of the very upper atmosphere.

So, now there are three zones that cause cooling. Moreover, if we then start to consider warmer air moving poleward, there will be significant areas where the CO2 is causing active cooling of the planet in total contradiction to the common assertion that CO2 always and inherently causes warming.


6 Responses to GreenHouse Effect

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  3. Damian Scott says:

    Hi Mike
    I don’t think you have this part quite right. The incoming short wave radiation from the Sun is not being absorbed/emitted by the atmosphere.
    The incoming radiation hits the ground which is absorbed causing Brownian motion (work) which causes longwave infrared radiation to be emitted and it is this that is absorbed and remitted by greenhouses gasses causing the greenhouse effect…as I understand it.
    Regardless of this, Greenhouse gasses are typified by their high emissivity. Increasing the proportion of greenhouse gasses in the atmosphere increases it’s emissivity which will increase the emissivity of the atmosphere. If you want to insulate anything you decrease it’s emissivity, it’s ability to achieve equilibrium with it’s environment.
    Proof of this is seen in the mid Tropospheric hotspot which turned out to be a coolspot, which is exactly what you would expect to see if greenhouse gasses increase the emissivity of the atmosphere and cause it to cool.

    Cheers

    • Scottish-Sceptic says:

      Damian thanks. Yes the heat is supplied by the incoming visible radiation, but the way to understand the greenhouse effect, is that the earth is stable when the average outgoing radiation temperature is that of the blackbody. So, if you average the temperature of all outgoing radiation it has to be equal to the blackbody temperature.

      The temperature of the various layers is created by the flow of heat through the atmosphere via convection because not much travels via IR in the atmosphere as it is so dense (except in the radiative windows). It’s only in the upper atmosphere that IR loss becomes dominant, which is why you need to think about the greenhouse effect from the top down and not the way many try to describe it which is from the bottom up.

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